Fe-sheathed MgB
2 superconducting tapes were prepared through an ex-situ process and powder-in-tube (PIT) technique using powders treated in organic acid solutions. The treatment realizes the substitution of carbon, derived from the remnants of the organic solvents being adsorbed onto the surface of MgB
2 grains, into boron in MgB
2 and pulverization of MgB
2grains. The amount of carbon substitution is
x = 0.02−0.03 in MgB
2-xC
x. The carbon substitution is effective for increasing
Bc2,and grain boundaries act as pinning centers. Therefore, this improves the
Jc property of tapes in the high-magnetic-field region.Depending on the solution, the
Jc values at 4.2 K and 10 T increase up to ten times compared to tapes using powders withouttreatment. These values are comparable to those obtained for the ex-situ processed tapes with the best-ever reported performance.Tapes using MgB
2-xC
x (
x ≥ 0.05) powders clearly show weak grain coupling, and hence the enhancement of transport
Jc is limited.
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