On a small forested watershed of sugi (
Cryptomeria japonica D. DON), the qualitative and quantitative vertical changes in water-chemicals were investigated in regard to precipitation, throughfall, soil water in seven layers, spring water, and stream run-off water, over a period of three years. Soil water was sampled using column lysimeters containing undisturbed soil. The precipitation, caused by the northwestern winter winds, contained much Cl
-, reaching a yearly peak concentration in precipitation and throughfall. By means of spectrum analyses, it was confirmed that the seasonal Cl
- concentration peaks in the soil water were caused by the downward movement of the peak in each upper layer with water infiltration. The height of the peak concentration became lower, and the range at the base of the peak became wider as the infiltration moved downward. The downward velocity of Cl
- was calculated to be 0.15_??_0.39cm/day through the time lag of the Cl
- peak appearance in each layer. The real downward water velocity, which was calculated based on the Cl
- peak velocity and the amount of run-off water through the lysimeters, was 0.28_??_1.06 cm/day more than that of Cl
-. The same seasonal trend for Na
+ as that for Cl
- was observed only on the surface and in the soil water in the shallow layers. The seasonal trend disappeared in the deeper layers because of the effect of Na
+ adsorption into the soil and its leaching from the soil. In run-off stream water, such seasonal trend did not appear because of the mixing of the water components, which passed along different run-off pathways.
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