Al-Si-based cast alloys are commonly used for engines and automobile transmissions. When Al-Si alloy is contaminated with Fe, Fe reacts with Al and Si during solidification, forming solid intermetallic compounds such as Al15Fe4Si2 and Al5FeSi. It is reported that Al5FeSi, which forms at high Fe content, significantly deteriorates the strength and elongation of Al-Si alloy. On the other hand, when Mn is added to an Al-Si alloy containing Fe, Al15(Fe,Mn)4Si2 precipitates instead of Al5FeSi. Therefore, the addition of Mn can suppress the harmful effect of Al5FeSi precipitation on the Al-Si alloy. In this study, to understand the forming conditions of Al15(Fe,Mn)4Si2 and Al5FeSi, molten Al-Si-Fe-Mn alloy was equilibrated with Al15(Fe,Mn)4Si2 and Al5FeSi, and the Fe and Mn contents of the alloy was investigated. Based on the experimental results, the forming conditions of Al15(Fe,Mn)4Si2 and Al5FeSi in molten Al-Si-Fe-Mn alloy during solidification were thermodynamically discussed. It was found that molten Al-12mass%Si alloy is saturated with both Al15(Fe,Mn)4Si2 and Al5FeSi at 850 K. The forming condition of β-Al5FeSi and the condition required to change Al5FeSi into Al15(Fe,Mn)4Si2 at 850 K were obtained as follows; [mass%Fe] > – 0.018 [mass%Mn] + 0.7 [mass%Mn] > 0.1 [mass%Fe] + 0.13
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