The mechanism of soil slaking is the breaking of soil aggregates by entry of water which is accompanied by salt releasing process when the soil contains salt. The objective of this paper is to describe the impacts of soil drying and slaking on cations release to outer solution and shift of cations during desalinization under different ini-tial water contents (IWC). A slaking test on natural and air-dried soils was carried out for evaluating the effect of slaking in different IWC (60, 50, 40, 30, 20 and 10 % by weight). After 24 hours immersion in water, Na was pre-dominantly released in every case both of the natural and air-dried soils. At the water content of 30 % that is around optimum slaking water content, maximum Na was released and at the water content of minimum slaking rate the re-lease of Na was lowest. However, too dry condition (10 % water content) did not contribute to release Na more. On the other hand, we did not find any special relationship be-tween the IWC and release of other cations like Ca, Mg and K in outer solution. Most of the Ca2+ and Mg2+ stay in exchange site (60 to 80 %) in soil and little amounts of them came out in outer solution. Water-soluble cations in slaked and unslaked soils followed the order of Na» K> Mg> Ca whereas, the amount of exchangeable state cations followed Na+ > Mg2+ > Ca2+ > K+. As a whole, the proportion of Na released in outer solution of natural soil was greater than that of air-dried soils. The results in-dicate that the water content for optimum slaking and the slower slaking rate is more efficient for desalinizing of Na from the saline soil.
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