Degradation kinetics of dichloromethane in water were investigated in a rectangular quartz cell under combination of UV irradiation and hydrogen peroxide (H
2O
2) addition. The presence of H
2O
2 not only enhanced the degradation rate of dichloromethane but prevented the formation of other chlorinated organic compounds as transient intermediates to mineralization. Since H
2O
2 was consumed by UV at a much higher rate than dichloromethane, it was found that the consecutive addition of H
2O
2 was highly effective to maintain high-rate degradation of dichloromethane. When 2,000 mg·
l-1 of H
2O
2 was added every 5 min, the decomposition rate of 1,500 mg·
l-1 dichloromethane exhibited 9.3 times higher than that of one-time addition of H
2O
2. Moreover, we successfully demonstrated that the degradation rate of dichloromethane was almost proportional to the square of incident light intensity.
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