This study is concerned with the mechanical properties in the vertical direction of the ozone-deteriorated nitrile rubber (NBR). NBR was sliced from the surface by a microtome. The crack behavior and mechanical properties were investigated as a function of depth, time and ozone concentration. Mechanical properties discussed in this study are tensile strength, tensile modulus of elasticity and elongation at break. There is a proportional relationship between the extent of deterioration and mechanical properties as
σ = (21.3
c+1.70) log
t · log
d + 14.5 ± 2.90,
where a is tensile strength (Mpa),
c is ozone concentration (ppm),
t is exposure time (hr) and
d is depth (mm) from the surface. If the ozone concentration was known, it is possible to estimate the time that the destruction occurs at a given depth from the surface. The crack increased significantly with the increase of ozone concentration. However, it was observed from the surface observation and the surface analysis by ESCA that the strength decreased only on a very thin surface.
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