The prominent feature of the Komaki Mine is the strongly developed supergene enrichment displayed about the Shirane deposit, spreading downward 200-300 meters from the surface of the deposits, and working particularly upon the primary sphalerite-galena zone and the underlying massive chalcopyrite zone disposed zonally in the western part of the deposits. This supergene enrichment formed large amounts of chalcocite, covellite and zinc sulphide mineral and accessory bornite, native copper and wittichenite(?).
The upper part of the enrichment zone is composed of a covellite-zinc sulphide association, and in the lower part a chalcocite-zinc sulphide association is prominently developed.
Paragenetic relations and modes of occurrence of these supergene minerals may be briefly summarised as follows:
1) The supergene enrichment is related to the zonal distribution of primary are minerals and complete lack of carbonate minerals, the existence of so-called black are type deposits within the immediate neighbourhood, and the distinct contrast in the nature of the veins in the eastern and western parts.
2) The supergene enrichment originated with zinc sulphide replacing the primary chalcopyrite, and thereafter continued to the formation of covellite, chalcocite→bornite. Then the excluded Zn ion was again deposited in zinc sulphide. It seems probable that the enrichment was controlled by the variation of pH and the ratio of[Zn¨]:[Cu¨]in the descending water.
3) The copper ion, which was consumed in the formation of chalcocite, covellite and bornite, was derived from the replacement of primary chalcopyrite by the supergene zinc sulphide.
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