The phase diagram of the Cu
2S-SnS system by the DTA method proved to be of simple eutectic type without a solid solution, and the eutectic point and the eutectic temperature were determined as 55 mol% Cu
2S-45 mol% SnS and 490°, respectively.
Also, vapour pressures of SnS of pure SnS, the Cu
2S-SnS and FeS-SnS systems were measured by means of the transportation method within a temperature range from 900 to 1, 100°, and activities of SnS in the two binary systems were calculated therefrom.
The activities of Cu
2S and SnS in the Cu
2S-SnS system exhibited a negative departure from the ideal behavior, but they were little changed by differences in temperature.
On the other hand, the activity of FeS and SnS in the FeS-SnS system deviated slightly positively from Raoult's law. This system could be regarded as a regular solution, and the following equation relating the Raoultian activity coefficient of SnS with composition and temperature has been obtained: ln
γSnS=438 (1-
χSnS)
2/T.
The activity coefficients at the infinite dilution of the components in the Cu
2S-SnS and FeS-SnS systems at 1, 100° were estimated as γ°
SnS=0.29, γ°
Cu2S=SnS=0.039 (Cu
2S-SnS system) andγ°
SnS=γ°
FeS=1.38 (FeS-SnS system), respectively.
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