Decomposition reactions of aqueous CN
- ions by TiO
2 photocatalyst, ozone and/or hydrogen peroxide were investigated. The principal findings obtained are as follows:
1) The presence of dissolved oxygen was necessary to decompose aqueous CN
- ions photocatalytically. CN
- was oxidized to CNO
- with TiO
2 catalyst, and then to CO
32- and NO
3-. Oxidation reaction of CNO
- to CO
32- and NO
3- was far slower compared to that of CN
- to CNO
-. Photocatalytic oxidation reaction of CNO
- at pHs 7 and 10 proceeded distinctly faster compared to that at pH 12.
2) Although ozone oxidation of CN
- took the same paths as photocatalytic reactions, but it was faster than that of photocatalytic routes. Combined use of photocatalyst and ozone for the decomposition of CN
- was more efficient.
3) Decomposition product of CN
- with hydrogen peroxide was found as CNO
- and N
2. Joint use of hydrogen peroxide and photocatalyst promoted reaction of CN
- to N
2.
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