The particle size distribution of powdered xerogel of silica and alumina ground in ball mills were investigated experimentally.
The silica xerogel powder used as the feed material was prepared in an ordinary way, that is, after granular silica xerogels being quenched with water several times, the resulting crushed granules were ball milled and clasified into several particle size regions by standard mesh sives.
And then samples of powdered xerogels were prepared by rearranging the fractions of each size regions, one of which was the region of tracer powder, so that they would from a normal distribution in particle size. The tracer powder colored by methylviolet consisted the largest size region. As for the alumina xerogel, a commercial micro sphere powder was used as the sample without any pre-treatment.
Results obtained are as follows:
1) Several particle regions with a discrete size distribution were found in the ground products. From a behavier of the tracer xerogel, this pulverizing process was made clear to proceed consecutively while each region was stable aggregates and easy to transfer into a finer region from a larger region. This fact is quite unusual compered with a conventional monomodal, continuous size distribution in a usual material.
2) The unusual size distributions were not dependent on the grinding conditions, but also a property (a physical texture) of the feed xerogel powder.
3) The new silica xerogel particles formed by grinding were begun to crush after a certain induction period in a grinding process. From these experimental results, it was found that the particles were at the first stage strained by mechanical force, followed by breaking into a smaller one.
4) The fact that the bulkiness of the powders has changed periodically with the increase of the grinding time, is explained with the gap grading theory of product powder, in this case, consisted of the two main discrete sized particles.
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