Some statistical quantities were experimentally evaluated for a system of droplets, which, because of their spherical shape, might be considered as idealized particles.
The droplets were prepared by atomizing an aqueous 5% NaCl solution through an atomizer of the paintspraying gun type or of the Lauterbach's nozzled-air flow type, and were allowed to stand tranquil or stirred for aging in a cylindrical mist chamber of a volume of about 0.23m
3. The droplet size was measured by means of our chemical spot method taking advantage of the formation of AgCl precipitate from a NaCl solution droplet, and was found to be heterogeneous in the limits of 0.5 and 6μ in diameter, depending on the conditions of atomization.
The results obtained are as follows: (1) The relation between a droplet diameter (
Dd) and its spot diameter (
ds) is expressed as
Dd3=0.541
ds2. (2) There is a close connection between the number of the droplets measured and the smoothness of the size distribution curve drawn; for a smooth curve to be found, it would be required to measure 500 droplets or more. (3) It is only necessary, in order to aquire a reliable number-averaged diameter for a comparatively homogeneous system having the relative standard deviation of 0.27, to measure 200 droplets or so, whereas it is needed to measure more than 500 droplets with definitely heterogeneous systems of the relative standard deviations larger than 0.46.
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