Although electroplating has been widely employed as a standard surface treatment for springs, some problems have still remained to be solved in relation to the embrittlement of electroplated coatings. For electrogalvanized coatings, Committee has made joint researches to understand the quantitative relationships between each electrogalvanizing step and embrittlement, to establish a system which can prevent embrittlement from occurring, and to evaluate embrittlement-prevention effect due to some baking conditions together with embrittlement by using actual springs.
The results are shown below.
(a) In the pretreatment step for electrogalvanizing, acid rinsing causes sever embrittlement, which can be effectively prevented by using inhibitors.
(b) Electrolytic degreasing rarely embrittles anodes and cathodes.
(c) The influence of the kinds of plating baths decreases in the descending order of chloride, zincate and cyanide baths.
(d) The system in which embrittlement occurs a little is as follows: Acid rinsing with a inhibitor added → anodic or cathodic electrolytic degreasing → zinc chloride bath.
(e) Wire springs to which wire drawing was applied undergo less embrittlement.
(f) As to heat treatment, oil quenching-tempering gives greater embrittlement than austempering.
(g) It is desirable for heat-treated products to be baked as enough as possible.
(h) With regard to the effects of flat spring hardnesses after heat treatment, the degree of embrittlement considerably decreases in the hardness-descending order of HRC52, HRC46 and HRC42.
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