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  • 眞保 良吉
    精密工学会誌
    2012年 78 巻 12 号 1038-1042
    発行日: 2012/12/05
    公開日: 2013/06/05
    ジャーナル フリー
  • 安達 秀雄
    日本獸醫學雜誌(The Japanese Journal of Veterinary Science)
    1961年 23 巻 2 号 125-130
    発行日: 1961/04/25
    公開日: 2008/02/13
    ジャーナル フリー
    Preventation of equine paratyphoid has been studied by many researchers, and variouskilled vaccines have been used, FIIRATO, and his associates, applied the AND0S chrometreatment [0 the preparatronr Of the vaccnne, and thC) reported that the
    chrome
    vaccine wasless toxic than the other killed vaccines, but that it caused abacterial suppuration after theintracutaneous injection, in the horse.The present studies of the
    chrome
    treatnnent were examined to remove the abovedrawback of the
    chrome
    vaccine, and the following results were obtained.1) Toxicity : Toxicity of the vaecirte was reduced by the
    chrome
    treatment with 8%
    chrome
    salts, as well as by 0.2%
    chrome
    salts.2) Suppuration : While forrnalin vaccine and O.2%
    chrome
    vaccine produced severeabacterial suppuration at the injection site, 8%
    chrome
    vaccine produced little or no suppura.tion but only a little induration.3) Antibody production : 8%
    chrome
    vaccine seemed to produce almost the samelevel of arrtibody later than did O.2%
    chrome
    vaccine, or formalin vaccine, irn rnice.
  • 眞保 良吉
    表面技術
    2014年 65 巻 3 号 123-128
    発行日: 2014/03/01
    公開日: 2015/03/01
    ジャーナル フリー
  • 福代 新治
    西日本皮膚科
    1974年 36 巻 4 号 467-468
    発行日: 1974/08/01
    公開日: 2012/03/24
    ジャーナル 認証あり
  • 濱 治慶, 寺尾 京平, 高尾 英邦, 下川 房男, 大平 文和, 鈴木 孝明
    IIP情報・知能・精密機器部門講演会講演論文集
    2014年 2014 巻 E-2-5
    発行日: 2014/03/18
    公開日: 2017/06/19
    会議録・要旨集 フリー
    Generally,
    chrome
    thin film is used for shading material of a photo mask. Pattern precision of the
    chrome
    mask is unstable in
    chrome
    wet etching, and process cost and environmental risk increase in
    chrome
    dry etching using chlorine gas. In this study, we investigate dry etching method using non-chlorine gas for the Cr mask patterning. Etch selectively between Cr thin film and protective resist treated by vacuum UV cure method were measured in electron cyclotron resonance plasma etching using Ar gas as inert gas.
  • 渡辺 和夫
    表面技術
    1999年 50 巻 2 号 149-154
    発行日: 1999/02/01
    公開日: 2009/10/30
    ジャーナル フリー
  • John Geraldine Sandana Mala, Balachandran Unni Nair, Rengarajulu Puvanakrishnan
    The Journal of General and Applied Microbiology
    2006年 52 巻 3 号 179-186
    発行日: 2006年
    公開日: 2006/09/06
    ジャーナル フリー
    Chromium toxicity is of prime concern due to
    chrome
    tanning processes in the leather sector.
    Chrome
    tanning results in the discharge of toxic levels of chromium causing pollution hazards. Chromium levels of Cr(III) and Cr(VI) were high above permissible limits in
    chrome
    samples after
    chrome
    tanning. The potential of Aspergillus niger MTCC 2594 to accumulate chromium as well as its biosorption capacity is investigated in this study. Bioaccumulation of Cr(III) and Cr(VI) in the spent
    chrome
    liquor has resulted in a 75–78% reduction of the initial Cr content in 24–36 h. A. niger biomass is found to be very effective in the biosorption of Cr(III) and Cr(VI) in spent
    chrome
    liquor. Maximum adsorption of 83% for biosorption of Cr(III) at 48 h and 79% of Cr(VI) at 36 h in spent
    chrome
    liquor is observed. The biosorption characteristics fit well with Langmuir and Freundlich isotherms and the adsorption parameters are evaluated. The biosorption of Cr also follows Lagergren kinetics. A. niger biomass is effectively used for the biosorption of chromium with 79–83% Cr removal in 36–48 h.
  • (第2報)クローム鞣に及ぼす陰電荷錯化合物の影響(その2)
    川村 亮, 和田 敬三, 山口 昭俊
    日本農芸化学会誌
    1952年 26 巻 12 号 650-654
    発行日: 1952年
    公開日: 2008/11/21
    ジャーナル フリー
    As cationic
    chrome
    [Cr(H2O)_??_]2 (S04)3, and as anionic
    chrome
    K[Cr(C204)2(H2O)2], K3[Cr (C204)3] were synthesized and used in the following experimeuts; i.e. after making hide powders work upon the solutions of each and the mixture of both, at pH 2.0, 4.0, 4.7, quautitative determinations of
    chrome
    , fixed to the hides, were doue. In addition,
    chrome
    -ch-rowate solutious corresponding to the formula Cr[Cr(C2O4)3], [Cr(C2O4)] [Cr(C2O4)2] were prepared, the same experimeuts were carried out and the relation of quantities to the sorts of ionic charge of combined
    chrome
    were discussed vdlency.
    The quantities of anionic chromes, fixed to hides with the progress of time were different from those of cationic; i.e. they were fixed to hide within short time and no increase of
    chrome
    was seen with the progress, of time but the cationic chromes were fixed to them- gradually with the progress of time.
    The quantities of Cr2O3 to the hide at pH 4.0, when the mixed solutions of
    chrome
    were used, were more larger than in the case of solution, when only one
    chrome
    wrs used. This phenomeno seems to have been caused by the fact that the solution contained [Cr(C2O4)]+ ion produced.
    The
    chrome
    complexs were fixed to the collagen at at different pH stages according to the sorts of charge and magnitude of valency. At lower pH value, the anionic chromes were fixed to hides withe almort the same quantities regardless of complex's valency, but at hig-her pH value those chrmoes which have higher valecies were decreased in quantity and that which have lower valencies were increased in quantity.
    On the other hand, the quantities of cationic chromes were fixed to them to a very small degree at lower pH value, but they acceleratively increased in quantity at higher. This tendency was remarkable to the
    chrome
    which have high complex's.
  • 石灰炉用耐火物の侵食機構 第2報
    太田 善造, 種村 文数, 月野 光秋
    石膏と石灰
    1960年 1960 巻 45 号 48-55
    発行日: 1960/03/01
    公開日: 2011/03/07
    ジャーナル フリー
    In the previous paper (Gypsum & Lime, No. 42, 9-18, 1959), the present authors have reported on the corrosion mechanism of lime kiln lining refractories by the X-ray diffraction and microscopic examinations. However, since the interactions between the chromemagnesite brick and lime at the corrosion test has been not at all reaction and also any sample bricks used in lime kilns have not been obtained due to be still more serving for long, petrological examinations have been carried out on the samples which previously had been added 5% to 30% of lime in the
    chrome
    -magnesite specimens. The results have been that a large amount of lime have been mainly affected to the
    chrome
    spinel grains in the
    chrome
    -magnesite specimens.
    In this paper, studied on interactions between
    chrome
    ores (50 mesh pass) and lime by X-ray diffraction and microscopic examinations for identifications of the occured minerals. The peterological examinations gave the following results :
    (1) In the low lime samples, less than 10% of lime, their mineralogical constitutions consisted of a large amount of unreacted
    chrome
    ore and a small amount of dicalcium ferrite (2CaO·Fe2O3) and monticellite (CaO·SiO2·MgO). In the high lime samples, more than 20% lime, consisted of unreacted
    chrome
    ore which reduced gradually with increasing of the added lime, dicalcium ferrite (2CaO·Fe2O3), tetracalcium aluminoferrite (brownmillerite, 4CaO·Al2O3·Fe2O3), calcium chromate corresponding to the mole ratio of CaO : Cr2O3=2 : 1, and in a certain ratio of lime, dicalcium silicate (2CaO·SiO2) or tricalcium silicate (3CaO·SiO2). In the 50% of lime, all
    chrome
    spinel grains did not remain and some free lime was present. The X-ray diffractometer curves of brownmillerite, dicalcium ferrite and the fired mixe corresponding to dicalcium chromate are considerably identical. Consequently, these compounds will be formed their complex solid solutions.
    (2) When the lime contents were larger than 20%, the lattice spacings of spinels in the
    chrome
    ores increased gradually with increasing added quantities of lime. The variation in lattice spacings of the spinels in the
    chrome
    ores will show that the constitutions of their spinel solid solutions changed due to a partial dissociation of them, and a small spacing spinel as MgO·Al2O3 would be ejected from the
    chrome
    spinel solid solutions owing to reducing the limited solid solubility of them.
  • 榎戸 真哉
    表面技術
    2018年 69 巻 6 号 230-233
    発行日: 2018/06/01
    公開日: 2019/01/01
    ジャーナル フリー
  • Kazuo Motizuki
    Journal of the Physical Society of Japan
    1959年 14 巻 6 号 759-771
    発行日: 1959/06/05
    公開日: 2007/06/01
    ジャーナル 認証あり
    Methylamine
    chrome
    alum shows an antiferromagnetic ordering below 0.015°K–0.02°K and it is known that this ordering results from the magnetic dipole-dipole interaction among the chromic ions. The present paper investigates, on the basis of the molecular field approximation, the phenomenon of transition below the Néel point from the antiferromagnetic state to the paramagnetic state caused by an applied field, at constant temperature or at constant entropy. Depending on the direction of the applied field relative to the crystalline axes and also on the shape of sample, different behaviours of the transition are obtained. For a spherical sample three are studied, namely, the cases of H\varparallel[111], H\varparallel[100] and H\varparallel[10\bar1], and for an infinitely long sample two cases, i.e., the axis of the sample and H are both parallel to either [111] or [100]. In Appendix is given a summary of the previous theoretical study by Kanamori. Motizuki and Yosida of the same kind of antiferro-paramagnetic transition in two-sublattice antiferromagnet, in relation to the present investigation.
  • 宗宮 重行
    窯業協會誌
    1965年 73 巻 843 号 235-244
    発行日: 1965/11/01
    公開日: 2010/04/30
    ジャーナル フリー
    The bursting expansion is one of the important disintegrations of the
    chrome
    bearing refractories and has been studied by synthetic spinels,
    chrome
    ores and
    chrome
    spinel grains separated from
    chrome
    ores.
    The mechanism of the bursting expansion is related to formation of solid solution and is one of the phenomena of the Kirkendall effect. (a) Formation of solid solution among spinel group minerals, (b) unequal diffusion coefficients of ions in the phases, (c) movement of Pt-mark in the sample, (d) displacement of Pt-mark during heating, inversely proportional to square root of diffusion time, (e) occurrence of pores in the refractories, and (f) expansion after heat treatment and/or reaction are evidences for the fact that the bursting expansion is the Kirkendall effect. By adopting the Kirkendall effect ast he mechanism of the bursting, it is able to explain of pores and expansion after heat treatment.
    The bursting expansions of synthetic spinel mixtures by a dilatometric method are divided into 3 types namely type E, type S and type L. Samples of the type E showed the bursting expansion, samples of the type S did not show the bursting expansion but showed shrinkage and samples of the type L showed a linear expansion up to 1600°C.
    In the case of the
    chrome
    spinel grains, there are 2 types of E and S for the bursting. The type E of the
    chrome
    spinel grains for the bursting belongs to the type C and A of TGA curves and the type S for the bursting showed TGA curve of the type B. The type C showed the largest bursting expansion among 3 types of A, B and C and the second expansion was shown by the type A. The type B did not show the bursting.
    Chrome
    spinel grains of No. 5 Inazumi, No. 2 Imobara, No. 12 Hinokami No. 18 Cuba and No. 19 Masinloc belonged to the type B, No. 1 and No. 6 Wakamatsu belonged to the type A and No. 3 Hatta, No. 4 Tomioto Shizunai, No. 7 Akaishi, No. 8 Philippine, No. 9 Philippine, No, 10 Hatta Main Mixture, No. 11 Tomimoto Nukahira, No. 13 Nitto, No. 14 Tsuchiya Horokanai, No. 15 Hatta Yawata, No. 16 Hatta Main, and No. 17 Nitto Washing belonged to the type C.
    The bursting expansions of the 15
    chrome
    ores by means of a bottom method were in the following order from large to small: No. 17 Nitto Washing, No. 13 Nitto, No. 10 Hatta Main Mixture, No. 9 Philippine, No. 1 Hirose, No. 6 Wakamatsu, No. 8 Philippine, No. 16 Hatta Main, No. 3 Hatta, No. 14 Tsuchiya Horokanai, No. 2 Imobara, No. 5 Inazumi, No. 7 Akaishi and the smallest No. 4 Tomimoto Shizunai.
    Diffusion coefficients of 59Fe at 1200°C and 1400°C in the system MgO⋅Cr2O3-iron oxide were D1200=2.89×10-11cm2/sec and D1400=3.69×10-10cm2/sec, respectively.
    We have to consider the following points as counterplans for the bursting expansion: (a) selection of
    chrome
    spinel grains from
    chrome
    ores, (b) content of
    chrome
    spinel grains in the refractory, (c) grain size, (d) calcination of
    chrome
    ore, (e) dense structure of the refractory, (f) porous structure and (g) others.
  • 種村 文数, 鍋田 恒之, 本多 徹
    石膏と石灰
    1978年 1978 巻 153 号 80-89
    発行日: 1978/03/01
    公開日: 2011/03/07
    ジャーナル フリー
    The high temperature zone of lime kiln is mainly occupied by magnesia-
    chrome
    brick, but the quality of magnesia-
    chrome
    brick depending upon the grade of natural chromite is coming to the limit of quality owing to its qualitative defects caused by natural chromite although the manufacturing technology was greatly improved besides the raw materials.
    Synthetic basic brick is epoch-making basic brick due to high purity synthetic bond having overcome the wall of quality of magnesia
    chrome
    by using synthetic special spinel clinker instead of chromite. The use of such synthetic basic brick instead of all kinds of magnesia-
    chrome
    bricks will promise a great development of brick life.
  • 白山 琢持, 上原 孝吉, 岡村 浩
    日本畜産学会報
    1989年 60 巻 7 号 653-658
    発行日: 1989/07/25
    公開日: 2008/03/10
    ジャーナル フリー
    北米産塩蔵成牛皮を使用し,靴用ソフト甲革を製造する素材としてのウエットブルー調製において,裸皮に対するクロム鞣剤(Cr2O3:25%)の使用量を2~8%の範囲で変え,クロム鞣剤の最適添加量を鞣剤の利用率と製品革の品質から検討すると共に,省クロム鞣しにおけるクロム削減効果について検討した.その結果,裸皮に対してクロム鞣剤添加量3%の場合にクロム利用率が78.8%と高く,品質良好の製品革が得られることを認めた.
  • 永井 淑晴, 樽本 敬三, 庄司 浜子
    金属表面技術
    1964年 15 巻 6 号 209-212
    発行日: 1964/06/20
    公開日: 2009/10/30
    ジャーナル フリー
    The mixing of chlorine into
    chrome
    plating bath is unavoidable in the process of decorative
    chrome
    plating.
    In this paper, it is reported mainly on the absorptiometric method by nitric acid saturated with silver chromate as well as the behavior of chlorine in
    chrome
    plating solution.
    In chromic acid solution, suspension is quantitatively formed by the reaction of the acid solution with Cl by adjusting the temperature and the concentration of nitric acid, and the absorbance can be measured at 800mμ with no effects of chromic acid.
    A process of reducing chlorate into chloride is essential for the estimation of chlorate.
    The content of chlorate is determined by the difference between the absorbance of reduced solution and that of original solution.
    The above method gives a good result for the simple and rapid analysis of a small amount of chlorine in
    chrome
    plating bath.
  • VII.グルコース還元液のアルカリによるクロム析出状況と陽荷電クロム量との関係
    先本 勇吉, 大杉 次男
    日本畜産学会報
    1958年 29 巻 3 号 184-187
    発行日: 1958年
    公開日: 2008/03/10
    ジャーナル フリー
    The glucose liquor was prepared by adding sulfuric acid to K2Cr2O7-glucose mixture with a different amount of glucose varying from the required amount for complete reduction to 200, 250 and 300% of the theoretically required amount under the best conditions for reduction efficiency.
    The precipitated
    chrome
    was determined by addition of an increasing volume of 0.1 N NaOH to 25 cc of 0.1% dilution of the
    chrome
    liquor. Then investigation was performed on the variation of maximum amounts of
    chrome
    precipitated by alkali and its relationship to the amount of cationic
    chrome
    which was absorbed by the cation exchanger, Dowex 50, X1.
    The results obtained are summarized as follows:
    1. The amount of precipitad
    chrome
    increased with the increase amount of alkali, reached the maximum value and then decreased, but a part of he
    chrome
    was not precipitated and remained in the liquor.
    2. The maximum precipitation amount, which was obtained by filtration after addition of alkali, nearly agreed with the amount of cationic
    chrome
    in the aged liquor.
    The agreement became less remarkable however, as the degree of dilution became higher.
    3. Both the maximum precipitation amount of
    chrome
    and the amount of cationie
    chrome
    showed the same tendency to decrease with the increase of glucose, but there was the difference of about 5% between them.
    It was found that 20-30% of total
    chrome
    contained in the glucose liquor used had not immed iately been precipitated by alkali.
    4. The maximum precipitation amount varied also with the amount of sulfuric acid.
  • Shoichi FURUHAMA, Yoshitane OYA, Takeichiro INOUE
    Bulletin of JSME
    1966年 9 巻 33 号 190-199
    発行日: 1966年
    公開日: 2008/02/15
    ジャーナル フリー
    The Cr-plated top piston-rings were irradiated, then the each amount of the radioactive wear debris of
    chrome
    and cast iron part were separately measured by mean of R.I. method. The main results of this investigation are as follows : (i) Wear of cast iron of the side faces is a several times or more as large than
    chrome
    of the sliding face. (ii) Wear of the cast iron is influenced sensitively by the oil-film-thickness. (iii) Additives of lubricating oil prevent mainly the carrosive wear, and its effectiveness is small when the normal runnig. (iv) When the piston-ring receive a high load, moreover the knock is occur, the wear is increased very sharply, specially the
    chrome
    part. (v) Dust is the most harmful, and air cleaner plays a very important part.
  • 山口 明良, 加藤 悦朗
    窯業協會誌
    1973年 81 巻 937 号 383-390
    発行日: 1973/09/01
    公開日: 2010/04/30
    ジャーナル フリー
    Several observations of the corrosion of
    chrome
    -magnesite and magnesite-
    chrome
    refractories by sodium carbonate vapor at 1200°C are described. One of the cause of the corrosion was that
    chrome
    ore being the main constituent mineral of these refractories was subjected to attack of sodium carbonate vapor. It was found that, at the early stage of the corrosion process, the grains of
    chrome
    ore decomposed into periclase and some compound to be expressed by following formula;
    Na2x (Si1-x, Xx) O2-Nay(Si1-y, Yy)O2 s. s.
    (2/5≤x≤1/2, 1/2≤y≤1, X: Mg2+, Fe2+, Y: Al3+, Cr3+, Fe3+)
    The compound was considered to have the derivative structure of cristobalite as well as carnegieite. As the supply of sodium carbonate vapor was continued, the compound changed into periclase and Na2CrO4.
  • 種村 文数, 本多 徹, 梶田 吉晴
    石膏と石灰
    1985年 1985 巻 197 号 211-217
    発行日: 1985/07/01
    公開日: 2011/03/07
    ジャーナル フリー
    Basic refractories have been used for the burning zone of the lime kiln. The texture of basic refractory such as magnesia-
    chrome
    brick is classified into silicate bond and direct bond. Besides magnesia-
    chrome
    brick, magnesia-spinel brick is common for the lime kiln. Many results have been obtained in the actual use of these refractories and it is known that life of the linings normally depends on the texture of refractories.
    Four different magnesia-
    chrome
    bricks in bonding texture and one magnesia-spinel brick were selected for the reaction test with lime. Samples were fired at 1400°C and kept for 4 hours in the test furnace.
    After reaction test, appearance observation, X-ray diffraction, chemical analysis, polarization microscope observation and reflection microscope observation were taken for the test. Especially, changes of micro-texture were observed.
    As the results, magnesia-
    chrome
    brick which has ideally developed direct bond showed the best behavior against lime. On the other hand the texture of magnesia
    chrome
    brick with silicate bond was decomposed by the migration of lime.
    On magnesia-spinel brick, spinel clinker (mainly MgO·Al2O3) in the brick reacted with CaO, consequently it became 12CaO·7Al2O3. This reaction may cause gradually the decomposition of the texture when the brick is used for a long time in the actual kilns.
  • 今井 順二, 濱田 糾, 上杉 徳照, 瀧川 順庸, 東 健司
    材料
    2008年 57 巻 2 号 105-111
    発行日: 2008年
    公開日: 2008/02/16
    ジャーナル フリー
    We investigated an optimizing process to improve hardness after the final heat treatment through modification by the Equal Cannel Angular Extrusion (ECAE) processing in a martensite stainless steel (corresponding to SUS420J2). We expected the more refinement in both the
    chrome
    carbide particles with relatively large sizes more than 0.5μm and the grain size of the matrix by the sever plastic deformation from the ECAE processing, by the way the less refinement in sizes of neither the particles or the grain size could be obtained than we expected. However, the lattice faults with a high density could be introduced into the matrix by the ECAE processing under the condition without any cracking along the interfaces between the
    chrome
    carbide and the matrix. It could accelerate drastically the ability in solid solution of the large
    chrome
    carbide particles into the matrix during the final heat treatment by quenching at higher temperatures more than 1323K that led successfully increasing the carbon mass in solid solution into the matrix. In the present study by optimizing the ECAE processing to accelerate the ability in solid solution of the large
    chrome
    carbide particles the hardness of the matrix could be improved to Hv = 700 from Hv = 600 achieved by the conventional process. We conformed an affectivity to enhance the hardness of the present martensite stainless steel by the modification from the ECAE processing.
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