Organic Chemistry Notes
Specific 5-Hydroxylation of Piperlongumine by Beauveria bassiana ATCC 7159
2012 年 76 巻 8 号 p. 1565-1567
詳細
2012 年 76 巻 8 号 p. 1565-1567
A new hydroxylated derivative was efficiently prepared by transforming the natural anti-cancer product, piperlongumine, with Beauveria bassiana ATCC 7159. Its structure was determined to be 5-hydroxylpiperlongumine on the basis of the spectroscopic data. The absolute configuration at C-5 was established as R by Mosher's method.
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