Agricultural and Biological Chemistry
Online ISSN : 1881-1280
Print ISSN : 0002-1369
ISSN-L : 0002-1369
Application of Dibenzoate Chirality Rule to Flexible Systems
Yukio YAMAMOTOMakoto FUSHIMIJun'ichi ODAYuzo INOUYE
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1975 年 39 巻 11 号 p. 2223-2226

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The chiroptical properties of (+)-(1S, 2S)-dibenzoxycycloheptane and (+)-(1S, 2S)-dibenzoxycyclooctane were observed. The dibenzoate chirality rule for chiral dibenzoxycyclohexanes was successfully applicable to these medium-sized ring compounds as well. The conformation of the open chain dibenzoates was discussed on the basis of the chiroptical properties found for the dibenzoate and di-p-nitrobenzoate of (+)-(2S, 3S)-butane-diol.
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