Agricultural and Biological Chemistry
Online ISSN : 1881-1280
Print ISSN : 0002-1369
ISSN-L : 0002-1369
Autoxidation and Photosensitized Oxidation of Methyl Eicosapentaenoate: Secondary Oxidation Products
Ryo YAMAUCHITomoo YAMADAKoji KATOYoshimitsu UENO
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ジャーナル フリー

1985 年 49 巻 7 号 p. 2077-2082

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Methyl eicosapentaenoate (methyl 5, 8, 11, 14, 17-eicosapentaenoate) was subjected to autoxidation and methylene blue-sensitized photooxidation. The secondary oxidation products were separated, and characterized by gas chromatography-mass spectrometry. The autoxidation products included hydroperoxy endoperoxide isomers, prostaglandin-like hydroperoxy bicyclic endoperoxide isomers and 5, 18-dihydroperoxide. The photosensitized oxidation products included only dihydroperoxide isomers as the secondary products.
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© Japan Society for Bioscience, Biotechnology, and Agrochemistry
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