Selective Electrocatalytic Oxidation of N-Alkyl-N-methylanilines to N-Alkylformanilides Using Nitroxyl Radical

Yoshitomo KASHIWAGI; Jun-ichi ANZAI

doi:10.1248/cpb.49.324

Notes

Selective Electrocatalytic Oxidation of N-Alkyl-N-methylanilines to N-Alkylformanilides Using Nitroxyl Radical

Yoshitomo KASHIWAGI, Jun-ichi ANZAI

著者情報

キーワード: mediator, nitroxyl radical, electrocatalytic oxidation, N-alkyl-N-methylaniline, N-alkylformanilide

ジャーナルフリー

2001 年 49 巻 3 号 p. 324-326

DOI https://doi.org/10.1248/cpb.49.324

詳細

抄録

Electrocatalytic oxidation of N-alkyl-N-methylanilines was studied using 4-benzoyloxy-2, 2, 6, 6-tetramethylpiperidinyl-N-oxyl as a nitroxyl radical. The reaction with N-alkyl-N-methylanilines led to direct formation of N-alkylformanilides in the presence of H₂O in reaction media in adequate conversion (>75.8%), high current efficiency (>89.2%) and high selectivity (>93.8%).

責任著者(Corresponding author)

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