Preparation of (Cyanomethylene)tributylphosphorane: A New Mitsunobu-Type Reagent

Izumi Sakamoto; Takeshi Nishii; Fumie Ozaki; Hiroto Kaku; Masami Tanaka; Tetsuto Tsunoda

doi:10.1248/cpb.53.1508

Notes

Preparation of (Cyanomethylene)tributylphosphorane: A New Mitsunobu-Type Reagent

Izumi Sakamoto, Takeshi Nishii, Fumie Ozaki, Hiroto Kaku, Masami Tanaka, Tetsuto Tsunoda

著者情報

キーワード: Mitsunobu reaction, (cyanomethylene)tributylphosphorane (CMBP), ylide

ジャーナルフリー

2005 年 53 巻 11 号 p. 1508-1509

DOI https://doi.org/10.1248/cpb.53.1508

詳細

抄録

(Cyanomethylene)tributylphosphorane (CMBP), which promoted the alkylation of various nucleophiles (HA) with alcohols (ROH) to give RA (Mitsunobu-type reaction), was prepared in two steps starting from chloroacetonitrile.

責任著者(Corresponding author)

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