THE STRUCTURE OF THE NEW DITERPENE ALKALOID NOMININE AND THE ABSOLUTE CONFIGURATION OF KOBUSINE

Shinichiro Sakai; Ichiro Yamamoto; Keiichi Yamaguchi; Hiromitsu Takayama; Miyuki Ito; Toshihiko Okamoto

doi:10.1248/cpb.30.4579

Shinichiro Sakai, Ichiro Yamamoto, Keiichi Yamaguchi, Hiromitsu Takayama, Miyuki Ito, Toshihiko Okamoto

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Keywords: absolute configuration

JOURNAL FREE ACCESS

1982 Volume 30 Issue 12 Pages 4579-4582

DOI https://doi.org/10.1248/cpb.30.4579

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Abstract

The structure of nominine (II), a minor diterpene alkaloid isolated from Aconitum sanyoense Nakai (native of Nomi, Kyoto prefecture) was established as 11-deoxykobusine by chemical transformation of kobusine (Ia) ; their absolute configurations have been established from CD spectral studies.

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