TOTAL SYNTHESIS OF ESTERS OF AK-TOXIN II AND AF-TOXIN IIC STARTING FROM VITAMIN C AS A CHIRAL MATERIAL

Hiroshi Irie; Kohei Matsumoto; Takao Kitagawa; Yong Zhang; Tamio Ueno; Tadakazu Nakashima; Hiroshi Fukami

doi:10.1248/cpb.35.2598

Hiroshi Irie, Kohei Matsumoto, Takao Kitagawa, Yong Zhang, Tamio Ueno, Tadakazu Nakashima, Hiroshi Fukami

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Keywords: phytotoxicity, host-specific toxin, vitamin C, chiral synthon, isoleucine, Wadsworth-Emmons reaction, Mitsunobu reaction

JOURNAL FREE ACCESS

1987 Volume 35 Issue 6 Pages 2598-2601

DOI https://doi.org/10.1248/cpb.35.2598

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Abstract

Total synthesis of the methyl esters of AK-toxin II and AF-toxin IIC, host-specific toxins to the susceptible cultivars Japanese pear and strawberry, was accomplished in optically active forms using vitamin C as a chiral material.

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