A Practical Synthesis of Arylthiocyanates from Arenesulfinates or Arenesulfonyl Chlorides with Cyanotrimethylsilane

Shinzo KAGABU; Keisuke SAWAHARA; Masaki MAEHARA; Sachiko ICHIHASHI; Katsuhiro SAITO

doi:10.1248/cpb.39.784

利部伸三, 沢原恵介, 前原雅樹, 市橋佐知子, 斉藤勝裕

著者情報

キーワード: sodium arenesulfinate, arenesulfinic acid, arenesulfonyl chloride, arylthiocyanate, cyanotrimethylsilane

ジャーナルフリー

1991 年 39 巻 3 号 p. 784-785

DOI https://doi.org/10.1248/cpb.39.784

詳細

抄録

Preparation of arylthiocyanates by simply mixing aromatic sulfinates with cyanotrimethylsilane (TMSCN) was achieved in good to moderate yields. The thiocyanates were also obtained directly from sulfonyl chloride using TMSCN, sodium sulfite, and potassium carbonate.

責任著者(Corresponding author)

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