(Cis)-PREFERENCE OF N, N'-DIMETHYL-N, N'-DIPHENYLGUANIDINE AND THE GUANIDINIUM SALT. CONSTRUCTION OF WATER-SOLUBLE AROMATIC LAYERED STRUCTURE

Aya TANATANI; Hiroyuki KAGECHIKA; Isao AZUMAYA; Kentaro YAMAGUCHI; Koichi SHUDO

doi:10.1248/cpb.44.1135

Aya TANATANI, Hiroyuki KAGECHIKA, Isao AZUMAYA, Kentaro YAMAGUCHI, Koichi SHUDO

Author information

Keywords: aromatic guanidine, guanidinium salt, N, N'-dimethyl-N, N'-diphenylguanidine, face-to-face conformation, aromatic architecture

JOURNAL FREE ACCESS

1996 Volume 44 Issue 5 Pages 1135-1137

DOI https://doi.org/10.1248/cpb.44.1135

Details

Abstract

N, N'-Dimethyl-N, N'-diphenylguanidine (2a) and the corresponding guanidinium salt (2b) have crystal structures in which two phenyl groups are located face-to-face. Similar (cis, cis) conformations were also observed in various solvents. These structures may be useful as key building blocks to construct water-soluble aromatic layered molecules.

Corresponding author

Register with J-STAGE for free!