Chemical and Pharmaceutical Bulletin
Online ISSN : 1347-5223
Print ISSN : 0009-2363
ISSN-L : 0009-2363
Studies on Metal Chelate Compounds of Phenazine Derivatives. II. Spectrophotometric Studies on Copper Chelate Compounds of 1, 6-Dihydroxyphenazine and its Di-N-oxide, Iodinin.
喜谷 喜徳
ジャーナル フリー

1958 年 6 巻 5 号 p. 563-566


Copper chelates of 1, 6-dihydroxyphenazine and its di-N-oxide, which possess two functional groups, were examined by spectrophotometric method concerning their properties and compositions in solution, as well as their dissociation constants. 1, 6-Dihydroxyphenazine forms a five-membered chelate ring, indicating the molar ratio of 1 : 1, a normal complex. The N-oxide derivative also form a chelate with molar ratio of 1 : 1, forming a six-membered chelate ring.

© The Pharmaceutical Society of Japan
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