抄録
9, 10-Dihydro-9, 10-phenanthrenediol cyclic phosphate (IV) was synthesized and its alcoholysis reaction with various hydroxylic compounds was investigated. The new cyclic phosphate was found to be alcoholyzed in acidic media by mono-and polyfunctional hydroxylic compounds, as well as by some aldoses, while the latter was found to be inert to the similar alcoholysis of hydrobenzoin or 4, 4'-dinitrohydrobenzoin cyclic phosphates. D-Ribose 5-phosphate was produced by this type of reaction. The intermediate phosphodiester-type compound in the above alcoholysis reaction, alkyl 9, 10-dihydro-9, 10-phenanthrenediol phosphate, was found to be not stable enough in acid media to be detected by paper chromatography.
