Electrochemistry
Online ISSN : 2186-2451
Print ISSN : 1344-3542
ISSN-L : 1344-3542
報文
Adsorption of Sulfur and Growth of Copper Sulfide on Cu(100) and Cu(110) in Alkaline Solution
Junji INUKAI, Masatoshi SUGIMASA, Shueh-Lin YAU, Kingo ITAYA
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2004 年 72 巻 6 号 p. 458-461

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Adlayer structures of S on Cu(100) and Cu(110) were investigated by using in situ scanning tunneling microscopy (STM) in alkaline solution. On Cu(100), the adsorbed S formed a structure, whereas a c(2 × 8) structure was found on Cu(110). Both structures were stable in the double-layer potential region. At anodic potentials, Cu2S was formed on both surfaces. On Cu(100), patches of islands with Cu2S(100) surfaces were observed. On Cu(110), the surface was highly roughened as a result of the formation of Cu2S.

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© 2004 The Electrochemical Society of Japan
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