[M(dmso)6][BPh4]2錯体[M=Co(II),          Zn(II)]の結晶相転移と配座解析

崎山 博史; 三橋 了爾; 御厨 正博; 脇 克志

doi:10.2477/jccj.2018-0019

Letters (Selected Paper)

Conformational Analysis for [M(dmso)₆][BPh₄]₂ [M=Co(II), Zn(II)] Showing Crystal-to-crystal Phase Transition

Hiroshi SAKIYAMA, Rjoji MITSUHASHI, Masahiro MIKURIYA, Katsushi WAKI

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Keywords: コバルト(II)錯体, 亜鉛(II)錯体, 結晶相転移, 配座解析, 配座異性体

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2018 Volume 17 Issue 3 Pages 153-154

DOI https://doi.org/10.2477/jccj.2018-0019

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Abstract

Based on the conformational analysis for an octahedral zinc(II) complex cation, [Zn(dmso)₆]²⁺ (dmso: dimethylsulfoxide), the crystal-to-crystal phase transition behavior of [Co(dmso)₆][BPh₄]₂ and [Zn(dmso)₆][BPh₄]₂ was discussed.

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