N-n-alkylethylenediamine have been prepared by the condensation of ethylenediamine with alkylbromides (C10C16). They were waxy, low-melting solids and combined with two equivalents of organic acids to form neutral salts which would be useful as cationic surfactants. Investigations were made on the surface activities of these salts with acetic, lactic and propionic acid. N-n-alkyl-ethylenediamine salts containing C10 and C16-alkyl group did not show good surface activities. On the other hand, N-n-dodecyl or N-n-tetradecylethylenediamine salts were found to have excellent surface activities. In respect of surface tension and penetrating power, acetates and lactates were superior, to the propionates, but inferior in foaming power.