ポリ塩化ビニル樹脂の帯電防止剤としてのポリオキシエチレンアルキロイルアミド金属錯塩

抄録

Several polyoxyethylene alkyloylamide metal complexes were synthesized from two moles of polyoxyethylene alkyloylamide and one mole of calcium, nickel, zinc, and cupric chlorides; and of calcium, nickel, and cupric acetates.
The effect of these metal complexes as internal antistatic agents for PVC was evaluated by measuring the frictional charge generation, induced charge decay and thermal stability.
The antistatic effect of polyoxyethylene mono- and diethanolamide was great, and the improvement of the effect by metal complexing was less.
Stearoyl derivatives were more effective than those having lauroyl group, and moles of ethylene oxide added showed little difference in 515 mole range.
Generally, the metal complexes with low frictional charge generation showed low induced charge and fast charge decay.