イソペンテニルメシチルオキシド並びにその加水分解によるメチルヘプテノンの合成
1983 年 32 巻 11 号 p. 700-703
詳細
1983 年 32 巻 11 号 p. 700-703
Alkylation of mesityl oxide (7) with 1-chloro-3-methyl-2-butene (1) using potassium or sodium hydroxide in an aprotic solvent afforded a mixture of isopentenyl mesityl oxide, (4), (5) and (9) in 83% yield, which were hydrolytically decomposed to 6-methyl-5-hepten-2-one (3) in 95% yield in an autoclave.
