Asymmetric Hydrogenation and Hydrogen Transfer Reactions Catalyzed by Chiral Transition-Metal Complexes

Hidemasa TAKAYA; Tetsuo OHTA; Kazushi MASHIMA

doi:10.5650/jos1956.39.10_866

油化学

Online ISSN : 1884-2003
ISSN-L : 0513-398X

J-STAGEトップ
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油化学
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39 巻 (1990) 10 号
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書誌

キラルな錯体による接触的不斉水素化, 不斉水素移動反応

高谷秀正, 太田哲男, 真島和志

著者情報

ジャーナルフリー

1990 年 39 巻 10 号 p. 866-874

DOI https://doi.org/10.5650/jos1956.39.10_866

詳細

抄録

Asymmetric catalytic hydrogenation and hydrogen transfer reactions of various functionalized olefins and ketones by use of BINAP-Ru (II) and BINAP-Rh (I) complexes have been reviewed. These asymmetric transformations have provided us new efficient routes to a variety of optically active organic compounds with important biological activity. Recent advances in the related field have been briefly summarized.