1999 年 16 巻 3 号 p. 229-238
From the standpoint of lubricative deficit under the alternative refrigerant/lubricants coexistence, the influence of additives on friction and wear characteristics for compressor parts have been investigated by the wear tester reappeared on friction condition similarly to actual compressor. It has been shown that an ester type base oil containing TCP (tricresyl phosphate) as an extreme pressure agents indicates satisfactory lubrication because of its EP effect. However owning to the deterioration of base oil caused by a cresol which is a reactant of TCP, a hydrolysis inhibitor must be necessary. The results indicates that a hydrolysis inhibitor added to POE is able to not only prevent the base oil from deteriorating but also feed the strength into oil films. On the other hands, in such a case that TCP concentration added in an alkylbenzen type base oil is excess or wear track temperature is higher, wear amounts of compressor parts are increased on account of corrosion wear. The reactivity of TCP depends on wear track temperature and its concentration. Consequently, it is possible that EP effect of TCP has been considered in terms of its concentration and temperature to be appropriated.