YAKUGAKU ZASSHI
Online ISSN : 1347-5231
Print ISSN : 0031-6903
ISSN-L : 0031-6903
有機水銀化合物の研究 (第12報)
ピリヂン-N-オキサイド及びキノリン-N-オキサイドの水銀化
鵜飼 貞二山本 讓平野 昌三
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1953 年 73 巻 8 号 p. 823-825

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Mercuration of pyridine 1-oxide with mercuric acetate, followed by treatment with sodium chloride yielded 4-chloromercuripyridine 1-oxide, m.p. 259-260°, which was confirmed by deriving it to 4-methoxypyridine 1-oxide. Mercuration of quinoline 1-oxide with mercuric acetate or mercuric perchlorate, followed by treatment with sodium chloride, yielded 8-chloromercuriquinoline 1-oxide, m.p. 235°, which was confirmed by deriving it to 8-bromoquinoline through its 1-oxide, m.p. 102-104°. 8-Bromoquinoline 1-oxide could not previously been obtained by any other method.
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© by the PHARMACEUTICAL SOCIETY OF JAPAN
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