YAKUGAKU ZASSHI
Online ISSN : 1347-5231
Print ISSN : 0031-6903
ISSN-L : 0031-6903
環状vic-ポリカルボニル化合物(第4報)1,1-ジフェニルシクロペンタンテトラオンの反応
山崎 恒義滝沢 武夫
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ジャーナル フリー

1973 年 93 巻 1 号 p. 1-7

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抄録
In dehydration of 1, 1-diphenylcyclopentane-tetrone dihydrate (1) and in dehydrogenation of 1, 2-dihydroxy-4, 4-diphenylcyclopentene-3, 5-dione (4), the formation of 1, 1-diphenylcyclopentane-tetrone (3) was detected. The compound 3 reacted with stilbene at its two adjacent carbonyl groups to give the 1, 4-cycloaddition products, 5 and 6. Dehydrating ability of 3 towards acenaphthene is comparable to that of ο-chloranil, and its redoxpotential was assumed to be 0.7-0.87 V.
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© by the PHARMACEUTICAL SOCIETY OF JAPAN
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