Phase-equilibrium studies of this system, at and just below temperatures where a liquid phase is present, show one ternary compound, the iron analog of cordierite (2FeO. 2Al
2O
3. 5SiO
2), which decomposes at 1210°±l0°C. to mullite, tridymite, and liquid. The fields of stability of corundum, mullite, hercynite, iron cordierite, cristobalite, tridymite, fayalite, and wüstite have been delineated. The following invariant points (the first two eutectics and the remainder reaction points) were located:
Fayalite+wüstite+hercynite+liquid 1148°±5°
Fayalite+iron cordierite+tridymite+liquid 1083°±5°
Fayalite+iron cordierite+hercynite+liquid 1088°±5°
Hercynite+iron cordierite+mullite+liquid 1205°±10°
Iron cordierite+mullite+tridymite+liquid 1210°±10°
Corundum+mullite+hercynite+liquid 1380°±5°
Cristobalite+tridymite+mullite+liquid 1470°±10°
Iron cordierite crystallizes with some reluctance, and the metastable invariant points fayalite+tridymite+spinel+liquid at 1073°±5°, and mullite+hercynite+tridymite+liquid at 1205°±10° can be realized. No ferrosilite or almandine garnet could be crystallized from the melts at any temperature even when melts were seeded with these crystalline phases. Natural almandine from Botallack, England (91. 3 per cent almandine), when heated begins to decompose at an appreciable rate as low as 900°C. and yields a mixture of hercynite, iron cordierite, and fayalite. The bearing of these results on petrology and slags is discussed.
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