PbO films were prepared by the oxidation of Pb films in oxygen and the photoconductive properties of these oxide films were investigated. The results are as follows:
(1) Pb films prepared by vacuum evaporation were almost completely oxidized by heatig for ten minutes at 450°C in oxygen. It was ascertained by X-ray analysis and conductivity measurement.
(2) The crystal structure of PbO was α-type and not β-type. Other types of lead oxides, i. e. , Pb
2O
3, Pb
3O
4, and PbO
2 were not contained in the prepared PbO.
(3) The relation between the photocurrent,
J and the intensity of light,
I is given by the following equation:
J=
k In, where
k is proportional constant independent on the intensity of light.
The values of
n varied from 1 to 0.5 with increasing intenslty of light, i. e.,
n is approximately equal to 1 at 20~150 luxes, 0.68~0. 75 at 250~8,000 luxes, and 0.5 at 8,000~30,000 luxes. Therefore, in the former, the recombination process is given as the kinetics of monomolecular reaction, while in the latter, the process is given as the kinetics of bimolecular reaction.
(4) Two peaks were observed in the photocurrent curve and one of them exists at 425 mμ and the other at 530mμ. The results coincide with the results of optical absorption.
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