Sensitized photocurrents were investigated in poly (N-vinylcarbazole) (PVK) films (~10 µ) on which thin dye layers (~0.1 µ) were deposited by means of vacuum evaporation. The porarity of majority carrier was found to be positive as well as in the non-sensitized photocurrent. A large spike was observed at the initial stage of photoconduction. This was attributed to a result of photoinduced charge transfer between the dye and the polymer. With rhodamine B as a typical of
n-type dye, electrons were injected from the dye to PVK, while with pyronine G, a
p-type dye, the spike appeared with the opposit polarity. The magnitude of these spikes were almost unaffected by the applied voltage. Oxygen or other electron acceptors depressed the spike and upraised the sensitized photocurrent. A sensitizing mechanism was proposed in which the electron injection from
n-type dye layer to traps in PVK layer precedes the hole injection, the main process of sensitization. This electron injection was presumed to facilitate the hole injection by compensating the local field existed at the dye-PVK interface.
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