The Mushu-Iwado and Momokawa failure-type slides of the Joetsu region, Niigata Prefecture, Japan, developed upon diagenetic alteration zones within sedimentary soft rocks of the Nakanomata Mudstone Member of the upper Miocene Noudani Formation and the Tsutsuishi Alternation of Sandstone and Mudstone Member of the Pliocene Kawazume Formation, respectively. The sedimentary soft rocks consist primarily of mudstone, sandstone, conglomerate and volcaniclastic rocks.
Core samples of sedimentary soft rocks from the Mushu-lwado and Momokawa landsLide areas were leached in aerated conditions to measure pH and concentrations of SO
42-, HCO
3-, Cl
-, Na
+, K
+, Ca
2+, Mg
2+etc.
The leachate pH of fresh rock ranges from 7.05 to 8. 90, while weakly, moderately and strongly weathered rocks record pH values of 6. 25 to 7. 22, 3. 01 to 6. 82, and 6. 20 to 6. 90, respectively. The leachate anions are predominantly SO
42-. The chemical characteristics of leachate are Na-SO
4 type in fresh, weakly weathered and strongly weathered rocks, and Ca-SO
4 type in moderately weathered rocks. Hexadiagrams of leachate from fresh, weakly weathered, moderately weathered and strongly weathered rocks reveal the chemical characteristics of each rock type. Na
+ concentrations exceed Ca
2+ in leachate from fresh rocks, but Ca
2+ is dominant in leachate from weathered rocks.
Smectite and smectite layers of interstratified illite/smectite minerals change from Na-type through Na-Ca-Mg-type to Ca-Mg-type during the progressive chemical weathering of the sedimentary soft rocks.
During chemical weathering, the porosity of the sedimentary soft rocks increases by approximately 5 to 10%, while the bulk density of the rocks decreases by approximately 0.2 to 0.4g/ml, and shear strength is reduced. These changes result from the consumption of pyrite, plagioclase and other minerals during the chemical weathering process.
Exceptional care should therefore be taken in managing and preventing Tertiary-type landslides within sedimentary soft rocks, as they are an especially hazardous environment.
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