We successfully fabricated
L2
1-ordered Mn
2VAl Heusler thin films and evaluated their ferrimagnetic properties by soft x-ray magnetic circular dichroism (XMCD). The buffer layers and annealing temperatures were varied to prepare the Mn
2VAl films. We discovered that Mn
2VAl could be ordered in an
L2
1 phase well when it was deposited directly onto an MgO (001) single crystalline substrate. The maximum values of
L2
1 and
B2 long-range order parameters we obtained were about 0.5 for both phases for samples without a buffer layer, when substrates were heated at 500°C or 600°C. The saturation magnetization (
Ms) for these samples was roughly 150 emu/cc. This is rather small compared to that expected from the ideal Slater-Pauling behavior, which might be due to the suppressed degree of
L2
1 or
B2 ordering. Ferrimagnetism in the Mn
2VAl, ferrimagnetic coupling between Mn and V moments was clearly observed by using the XMCD technique in well-ordered
L2
1-Mn
2VAl film as has been predicted in theoretical investigations.
View full abstract