Journal of the Magnetics Society of Japan
Online ISSN : 1882-2932
Print ISSN : 1882-2924
ISSN-L : 1882-2924
Volume 47, Issue 6
Displaying 1-1 of 1 articles from this issue
Thin Films, Fine Particles, Multilayers, Superlattices
  • S. Wang, H. Onoda, J. Harbovsky, H. Yanagihara, J. Inoue, M. Veis, T. ...
    2023 Volume 47 Issue 6 Pages 137-143
    Published: November 01, 2023
    Released on J-STAGE: November 01, 2023
    Advance online publication: August 10, 2023
    JOURNAL OPEN ACCESS

      The magneto-optical (MO) spectra of spinel cobalt ferrite thin films with different distortions were measured in a broad range of 0.59 – 3.54 eV. Instead of using the cation substitution method, we prepared cobalt ferrite thin films with local distortion by using a RF magnetron sputtering method on an Mg2SnO4 buffer layer to induce epitaxial strain. We derived the diagonal and off-diagonal elements of the dielectric tensor to investigate the influence of distortion on the MO effect in the films. In the spectra of the off-diagonal dielectric elements, the transitions at 0.8, 1.8, and 2.0 eV, which correspond to the optical transitions of tetrahedral (Co2+) and octahedral [Co2+], [Fe3+], were assigned to crystal field (CF) transitions: (Co2+): 4A24T1(F), 4A24T1(P) and intervalence charge transfer (IVCT) transition: [Co2+]t2g → [Fe3+]t2g, respectively. This result revealed that the Co ions were present in both the tetrahedral and octahedral sites in the epitaxial CFO thin films. By comparing the relative amplitude of each MO transition of cobalt ferrite thin films with different distortions, we found that MO spectroscopy is a highly promising tool for evaluating local distortions.

    Download PDF (1139K)
feedback
Top