By using a low temperature plasma carburising process combined active screen and DC plasma methods at 773 K under an atmosphere of CH4/H2 gas mixture, an expanded-austenite phase (called the S phase) that has both high hardness and high resistance to corrosion can be efficiently formed at the surface of austenitic stainless steels. In this paper, effects of the S phase formed in SUS304 and 316 steels on microstructure, tension, and oscillation wear properties were investigated by optical microscopy, x-ray diffraction (XRD) analysis, transmission electron microscopy (TEM) observation, a tensile test, and reciprocating ball-on-disc tribometer (SRV) test. The results show that the S phase includes high-density dislocations, has a high amount of twins and stacking faults, and improves tensile strength while decreasing the elongation. The S phase was also found to improve frictional wear and fretting wear resistances of austenitic stainless steels.
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