The effect of carbon content in iron on the stability of
γ′ and
ε phases in the Lehrer diagram was investigated by the thermodynamic equilibrium calculation using CALPHAD method. The low alloy steels with different carbon content of 0.1 mass%, 0.45 mass% and 1.0 mass% were adopted for gas nitriding, and their nitrided phases were identified. The
ε- phase is stabilized at lower nitriding temperature and with lower nitriding potential as the increase of the carbon content, while the
γ′-phase is unstabilized there. The phases in the gas nitride layer of the steels showed a good agreement with the calculation result of 0.1%C containing steel. Decarburization during the nitriding may be responsible for the insensitive with carbon content of the steels.
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