The study of a pyrochemical process by using alkalis molybdate melt has been carried out as a candidate reprocessing process for spent oxide fuels. In the previous studies, the UO
2 pellet was dissolved into molten Na
2MoO
4-MoO
3 mixtures and the dissolved uranium species in the melts were recovered by electrolysis. However, in a MOX dissolution test, we observed that iron species were dissolved into the melts from the stainless steel cladding tubes. The immersed corrosion tests of SUS316 tubes were thus carried out in molten Na
2MoO
4-MoO
3 mixtures with MoO
3 mole fractions ranging from 0.02 to 0.50 at 1023 K. Results showed that the concentration of dissolved iron and nickel species in the melt increased with an increase in MoO
3 mole fraction, whereas the concentrations of dissolved chromium species remained low, independent of the MoO
3 content. The cross-sectional morphology of the SUS316 specimen immersed for 2 h in the molten 0.5Na
2MoO
4-0.5MoO
3 mixture at 1023 K clearly showed a layer of 22-29 nm thickness with a high content of chromium formed at the surface of the SUS316 specimen. It was thus found that the corrosion of SUS316 specimens in molten Na
2MoO
4-MoO
3 mixtures at 1023 K proceeds with the iron and nickel preferably dissolved into the melt and with chromium-rich corrosion films formed at the surface.
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