高級脂肪酸エステルと金属ナトリウムとの反応 (第7報)
オレオイン, sym-ジヘプタデセニルエチレングリコールの合成ならびに性状
1961 年 10 巻 9 号 p. 565-568
詳細
1961 年 10 巻 9 号 p. 565-568
The unsaturated acyloin corresponding to oleoin was prepared from methyl oleate by the reductive condensation reaction with metallic sodium. Oleoin could be reduced by lithium aluminium hydride or aluminium iso-propoxide, giving unsaturated α-glycol which corresponds to sym-diheptadecenyl-ethyleneglycol.
The properties of both compounds compared with saturated products were discussed.
