脂肪族過酸化物とハロゲンの反応に関する研究 (第4報)
シクロヘキサン溶媒中におけるジオクタノイルペルオキシドと四臭化炭素の反応
1966 年 15 巻 1 号 p. 17-20
詳細
1966 年 15 巻 1 号 p. 17-20
The reaction of dioctanoyl peroxide with carbontetrabromide in cyclohexane was studied.
In this reaction, dioctanoyl peroxide behaved as the initiator of the radical reaction of cyclohexane with carbontetrabromide, and cyclohexyl bromide was produced according to the radical chain mechanism. The yield of cyclohexyl bomide was 85.8% at optimum condition (dioctanoyl peroxide/carbontetrabromide 1/1mol; concentrations of dioctanoyl peroxide and carbontetrabromide in cyclohexane 1mol%, respectively; reaction temperature 70°C; reaction time 24hr). By-products of this reaction were 1-heptyl bromide, tetradecane, caprylic acid, bromoform and dibromomethane, etc.
