非水系における単一及び混合極性物質と逆ミセル間の相互作用に関する研究
1981 年 30 巻 12 号 p. 849-853
詳細
1981 年 30 巻 12 号 p. 849-853
The interaction of single components and mixtures of methanol, ethanol, acetone, methyl acetate, ethyl acetate, and acetic acid with the reversed micelles of Aerosol OT and dodecylammonium propionate in toluene or cyclohexane were investigated. The concentration of free polar substances in the medium was measured at 20.0, 27.5, and 35.0 by the gaschromatographic method. The binding constants and the change of thermodynamic quantities (ΔG°, ΔH°, and Δ S°) for the interaction between the polar substances and the reversed micelles were obtained from these data.
