1984 年 33 巻 1 号 p. 58-60
Fluorination of various terpenic alcohols and fatty alcohols with N, N-diethyl-1, 1, 2, 3, 3, 3-hexafluoropropyl amine (PPDA) was carried out. A mixture of 2- (2'-fluoroethyl) -6, 6-dimethyl-bicyclo [3.1.1] hept-2-ene (2) and nopyl 2, 3, 3, 3-tetrafluoropropionate (3) was obtained from the reaction of nopol (1) with PPDA. Similar results were obtained from other terpenic alcohols and fatty alcohols.