フェロセン修飾界面活性剤による有機薄膜の作製

抄録

This review describes the preparations and the properties of organic thin films by the controlled-potential electrolysis during the oxidation of an aqueous solution containing surfactants with a ferrocenyl moiety and organic compound incorporated in micelles (Scheme I) or dispersed organic particles using the surfactants (Scheme II).Films of azo dyes, 4, 4'-didodecylviologen and some polymers are prepared through Scheme I. Films of phthalocyanine compounds, MPc (M=H₂, Cu, Mg, and AlCl), and halogen derivatives of CuPc, are prepared through Scheme II. The scanning electron micrograph studies show that crystal size of the film increases with electrolysis time in the case of Scheme I and is the same for the added particles in the case of Scheme II.