The effect of hydrogen on general corrosion of pure iron and ferritic steels, Si-Mn alloy and Mn-Mo alloy, was investigated in acid solutions. Hydrogenation was carried out in 10-280atm hydrogen at 450°C for 16hr. Corrosion loss of ferritic steels containing hydrogen was markedly greater than that of hydrogen-free specimens, and increased with increasing hydrogen content. Anodic polarization curves of pure iron and Si-Mn alloy steel containing hydrogen in 1N-H
2SO
4 solution exhibited an increase of current density in the passive region in agreement with corrosion data. These anomalous corrosion was partly recovered by dehydrogenation heating at 300-950°C. Deformation increased the occluded hydrogen content and anomalous corrosion loss. The anomalous corrosion was only responsible for the residual hydrogen content independent of the structure. It is suggested that the anomalous behavior is caused by activated internal microdeffects formed by hydrogen trapping.
View full abstract