Metallurgical examination and simulation test of stress corrosion cracking (SCC) were carried out to reveal the cause of SCC of Hastelloy C test vessel in hot concentrated sodium chloride solution The following results were obtained.
(1) SCC occurs from pits and develops along grain boundaries at which intermetallic compounds such as P phase and Ni
7Mo
6 precipitated because of welding heat or heat treatment.
(2) Susceptibility to intergranular corrosion at precipitated grain boundaries is very high in oxidizing environment.
(3) The brittle mode of intergranular fracture with geometric pattern was observed on the SCC fractured surface of the heat treated specimen. It seems that such mode was formed due to the effect of precipitated phases.
(4) From the point of view of the material, residual stress due to welding and high susceptibility to intergranular corrosion due to precipitation of intermetallic compounds are dominant as a cause of SCC. From the point of view of environment, diffusion of reactive species in solution such as concentration of chloride ion and supply of oxygen is dominant.
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