The principal co-precipitation mechanism of radioactive strontium with barium sulfate is the isomorphous replacement between Ba
2+ and Sr
2+ in the crystal. Thus, the removal ratio of radioactive strontium from an aqueous solution depends on the equilibrium constant, solubility product and quantities of barium sulfate, and SO
42- concentration.
In low salt concentration, the equilibrium constant,
K, for barium sulfate which was prepared with the reaction of Ba
2+ and SO
42- in the test solution was 1.9×10
-4. On the other hand, the equilibrium constant for powdered barium sulfate added was
Ks=9.1×10
-6.
In a high salt concentration less than about 3×10
-1mol/
l NaCl and NaNO
3, and less than about 1.0mol/
l Na
2SO
4, the experimental removal ratio agrees with the calculated values. But in high salt concentrations ranging from 3×10
-3mol/
l to the saturated concentration of NaCl and NaNO
3, ranging from 1.0mol/
l to the saturated concentration of Na
2SO
4, the experimental removal ratio decreases.
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